• ASTM D5600-14

ASTM D5600-14

Standard Test Method for Trace Metals in Petroleum Coke by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES)

ASTM International, 06/01/2014

Publisher: ASTM

File Format: PDF

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Published:01/06/2014

Pages:5

File Size:1 file , 81 KB

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1.1 This test method covers the analysis for commonly determined trace metals in test specimens of raw and calcined petroleum coke by inductively coupled plasma atomic emission spectroscopy.

1.2 Elements for which this test method is applicable are listed in Table 1. Detection limits, sensitivity, and optimum ranges of the metals will vary with the matrices and model of spectrometer.

Element

Wavelengths, nmA ,B

Concentration
Range, mg/kgC

Aluminum

237.313, 256.799, 308.216, 396.152

15-110

Barium

455.403, 493.410

1-65

Calcium

317.933, 393.367, 396.847

10-140

Iron

259.940

40-700

Magnesium

279.079, 279.553

5-50

Manganese

257.610, 294.920

1-7

Nickel

231.604, 241.476, 352.454

3-220

Silicon

212.412, 251.611, 288.159

60-290

Sodium

588.995, 589.3, 589.592

30-160

Titanium

334.941, 337.280

1-7

Vanadium

292.402

2-480

Zinc

202.548, 206.200, 213.856

1-20

(A) The wavelengths listed were utilized in the round robin because of their sensitivity. Other wavelengths can be substituted if they can provide the needed sensitivity and are treated with the same corrective techniques for spectral interference (see 6.1). In time, other elements may be added as more information becomes available and as required.
(B) Alternative wavelengths can be found in references such as “Inductively Coupled Plasma Atomic Emission Spectroscopy,” Winge, R. K., Fassel, V. A., Peterson, V. J., and Floyd, M. A., Elsevier, 1985.
(C) Based on this round robin study. This test method can be applicable to other elements or concentration ranges but precision data is not available.

1.3 This test method is applicable only to samples containing less than one mass % ash.

1.4 Elements present at concentrations above the upper limit of the working ranges can be determined with additional, appropriate dilutions.

1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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