• ASTM D7979-17

ASTM D7979-17

Standard Test Method for Determination of Per- and Polyfluoroalkyl Substances in Water, Sludge, Influent, Effluent and Wastewater by Liquid Chromatography Tandem Mass Spectrometry (LC/MS/MS)

ASTM International, 07/15/2017

Publisher: ASTM

File Format: PDF

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Published:15/07/2017

Pages:27

File Size:1 file , 360 KB

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1.1 This procedure covers the determination of selected per- and polyfluoroalkyl substances (PFASs) in a water matrix using liquid chromatography (LC) and detection with tandem mass spectrometry (MS/MS). These analytes are qualitatively and quantitatively determined by this method. This method adheres to a technique known as selected reaction monitoring (SRM) or sometimes referred to as multiple reaction monitoring (MRM). This is not a drinking water method, performance of this test method has not been evaluated on drinking water matrices.

1.2 The Method Detection Limit (MDL)2 and Reporting Range3 for the target analytes are listed in Table 1. The target concentration for the reporting limit for this test method was 10 ng/L for most of the target analytes at the time of development.

AnalyteA

MDL
(ng/L)

Reporting Ranges
(ng/L)

PFTreAB

1.2

10 - 400

PFTriAB

0.7

10 - 400

PFDoAB

1.2

10 - 400

PFUnAB

1.2

10 - 400

PFDAB

1.4

10 - 400

PFOSB

2.2

10 - 400

PFNAB

1.1

10 - 400

PFecHSB

1.9

10 - 400

PFOAB

1.7

10 - 400

PFHxSB

1.2

10 - 400

PFHpAB

1.0

10 - 400

PFHxAB

2.0

10 - 400

PFBSB

0.8

10 - 400

PFPeAB

4.6

50 - 2000

PFBAB

4.6

50 - 2000

FHEA

92.9

300 - 8000

FOEA

106.8

300 - 8000

FDEA

47.2

200 - 8000

FOUEA

2.3

10 - 400

FHpPA

3.3

10 - 400

FHUEA

1.5

10 - 400

(A) Acronyms are defined in 3.3.
(B) New MDL study was reported in August 2016, which resulted in a reporting limit and range update.

1.2.1 The reporting limit in this test method is the minimum value below which data are documented as non-detects. The reporting limit may be lowered providing your lab meets the minimum performance requirements of this test method at the lower concentrations, this method is performance based and modifications are allowed to improve performance. Analyte detections between the method detection limit and the reporting limit are estimated concentrations and are not reported following this test method. In most cases, the reporting limit is the concentration of the Level 1 calibration standard as shown in Table 4 for the

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